Hot and cold lime soda process pdf

Limesoda water softening process and its advantages notes pdf ppt. Calculate the amount of lime 85% pure and soda 95% pure required to soften one million litre of water which contains caco 3 12. Lime soda softening process can be carried out at ambient temperatures known as cold lime soda treatment or at temperatures close to the boiling point f water known as hot lime soda treatment. Hot lime soda is rapid process and cold lime soda is slow process in hot lime soda coagulant does not require in cold lime soda coagulant is required 5. Plants a, b, c and d use another method of clarification called lime softening. Hot lime soda process is much faster than the cold lime soda process. The hot lime soda process water softener systems are exclusively used for boiler. Cold lime soda process cold lime soda process is a watersoftening process in which water is treated with hydrated lime sometimes in combination with. Hot end treatment is applied before the annealing process.

It also explains how cold lime softening works, and provides guidance on maintaining system reliability. The types of lime soda softening process include the use of lime caoh 2 with soda ash na 2 co 3, the use of caustic soda naoh and the use of quick lime cao with soda ash na 2 co 3. What is the hot lime soda process of water treatment. The hot and cold soda lime processes 1 2 are used to reduce the mineral content of water and soften it on an industrial scale and community water treatment. The basic principle in this method is to convert all the soluble hardness causing constituents into insoluble precipitates by appropriate chemical reactions. Chemistry of limesoda softening of cooling water northeastern. The practical calcium solubility limit is 35 ppm as caco 3 and the practical magnesium solubility limit is 75 ppm as caco 3 using cold lime soda treatment. Less cost than lime soda softeners, easier to control and chemicals used safer for operators. Cold lime softening process is used to reduce raw water hardness, alkalinity, silica, and other constituents.

Cold lime soda process free download as powerpoint presentation. This process is operated at a temperature close to the boiling point of the solution 3. Cold limesoda process article about cold limesoda process. Soda ash is used to remove chemicals that cause noncarbonate. What is the difference between hot lime soda and cold lime. The lime soda process involves the chemical conversion of all the. Lime softening lime buttering or lime soda treatment also known as clarks process, is a type of water treatment used for water softening which uses the addition of limewater calcium hydroxide to remove hardness calcium and magnesium ions by precipitation.

Aug 28, 2011 cold lime soda process hot lime soda process 1. Rely on the principles of ion exchange to soften water. Softening of water by hot and cold lime soda method and. Addition of lime cao and soda na 2 co 3 to the hard water precipitates calcium as the carbonate, and magnesium as its hydroxide. Filtration of the precipitates formed is difficult. Cold lime softening sewage treatment reverse osmosis. The chemical mixing process is same as the cold lime soda process, but steam is applied in mixture tank. Tin oxide coating is applied as a hot end treatment. Solids contract unit differentiate between gravimetric and volumetric dry feeders. The process is also effective at removing a variety of microorganisms and dissolved organic matter by flocculation. This helps prepare water for direct use as cooling tower makeup or as a firststage treatment followed by ion exchange for boiler makeup or ro reject recycle.

Therefore, they are more effectively removed by warm lime softening than by cold lime softening. This process is more effective than cold lime soda process. As a result precipitation becomes almost complete very quickly. The precipitation reactions with lime and soda are very slow. Reactor reactions and stoichiometry of lime softening 2 lime in the name of lime softening is based on it being the main added chemical in this process. Why is hot limesoda process preferred over cold limesoda. Methods of protection against corrosion viz proper designing. In the lime soda ash process, lime is added to raise the ph while sodium carbonate is added to provide a source of. C, the soluble ca and mg salt present in hard water are chemically converted into ppt. For large volume water softening, the traditional process is called cold hot lime softening and no any alternative processes have not been yet success to abandon it 1. In this process, water is treated with softening chemicals like soda and lime at a temperature of 80 0 c and 150 0 c. Also used in the preparation of caustic soda naoh, by mixing slaked lime caoh 2. In this process, a suspension of calcium hydroxide lime and sodium carbonate soda is added.

Lime cannot remove the calcium permanent hardness which should be removed by soda. The water chemist distinguishes between cold process lime softening, usually carried out in the range of 40 to 9o0f 4 to 320c, and hot process, at 215 to 23o0f 102 to 11o0c. This process is now obsolete but was very useful for the treatment of large volumes of hard water. Why is hot lime soda process preffered over cold lime soda. This twoyear study outlines the transition from excess lime to straight lime softening, and its effects on operational costs and water quality.

Compare between continuous cold and hot lime soda process. A watersoftening process in which water is treated with hydrated lime, which reacts with dissolved calcium and magnesium compounds to form precipitates. Therefore, soda ash sodium carbonate must be externally added to precipitate this remaining calcium. The precipitated caco 3 and mgoh 2 are filtered off. Unit 6water treatment chapter 1 external boiler water.

A cost effective technique for chemical wastes reduction in. The coagulant may be supplemented by an anionic or a nonionic flocculant. Hot lime soda process in the hot lime soda process the reactions take place at higher temperature near about boiling point of water. At room temperature, the precipitates formed are finely divided, so they do not settle down easily and cannot be filtered easily. Three important industrial methods employed for softening of water are. The aim of the lime soda process is to convert calcium and magnesium compounds to the virtually insoluble forms, calcium carbonate caco 3 and magnesium hydroxide mgoh 2. Cold lime softener cls, warm lime softener wls, and hot lime softener hls. Limesoda ash softening is a well established water treatment process. Calculate the quantity of lime and soda needed for softening of 50,000 litres of water. Aug 17, 2020 thorlabs soda lime hot mirrors are perfect for keeping unwanted heat from reaching sensitive areas of your setup.

Lime soda ash softening process 10 when lime and soda ash are added, hardnesscausing minerals form nearly insoluble precipitates. This article first covers how gravity clarifiers work, some of the chemicals used in clarification, proper chemical feeding procedures, and clarifier equipment designs. Cold or warm process softening is not as effective as hot process softening for silica reduction. As you may notice, this classification is based on the operating temperature of the system, though there is not a clear and cut distinction between them. Explain hot and cold lime soda process with the help of. In extreme cases, the postprecipitation occurs in the heat exchangers. A cost effective technique for chemical wastes reduction.

These are formed by substances which have greater solubilities in hot water than in cold water. In this method, the soluble calcium and magnesium salts in water are chemically converted in to insoluble compounds, by adding calculated amount of lime and soda. If process is carried out at room temperature it is called cold lime soda process. Lime is used to remove chemicals that cause carbonate hardness. For calcium removal, the required lime and soda ash dosages are calculated by sto chiometry. In the lime soda ash process, lime is added to raise the ph while sodium carbonate is added to provide a source of carbonate ion. Cold lime soda process lime soda process water treatment. The most common gravityclarification process is cold lime softening. Why coagulant is not used in hot lime soda process instead. In applications where heat build up is a concern, 0 or 45 angle of incidence aoi hot mirrors provide a means of protection by reflecting the ir beam either back along the in. Treatment applied in this fashion actually reacts to the glass, and cannot be washed off. Hot and cold lime soda process 10th lecturer by ruchi.

However, added magnesium oxide and good sludge contact will improve results. Hi, i am mohan dangi welcome to our youtube channel digitech education about video. Limesoda water softening process and its advantages notes. If the dissolving of the chemical in water is an exothermic process and releases heat energy, it is a good candidate for making a hot pack because this process will raise the. Lime soda softening consumes huge amount of lime, caustic soda, soda ash and. In the limesoda process enough lime and soda are added to the raw water to. When the hot process limesoda treatment is used, there is the.

Definition and its significance, theories of corrosion, galvanic cell and concentration cell. Lime reacts with temporary hardness, co 2, acids, bicarbonates and alums. Cold lime soda process, when hard water is treated with calculated amount of lime caoh 2 and soda ash na 2 co 3 at room temperature 25. Dec, 2018 scouring processes the lime soda process milk of lime is used caoh2 the liquor is heated to 1200c at 1. Methods of boiler water treatment lime soda process hot and cold lime soda process, permutit or zeolite process, deionization or demineralization. Chemical precipitation is one of the more common methods used to soften water. Caco3 and mgoh2 so precipitated, these precipitates are filtered off. Predicted analyses of a typical raw water treated by various lime and lime soda softening processes are presented in table 71. The process can be worked hot 7090c or cold, the former usually giving. In the lime softening process, the ph of the water being treated is raised sufficiently to precipitate calcium carbonate and, if necessary, magnesium hydroxide. Only calculated amounts of lime and soda are to be added.

Chemistry of soda lime process as slacked lime is added to a water, it will react with any carbon dioxide present as follows. Mar 03, 2014 hot and cold lime soda process 4 332014. A 230v, singlephase, 60hz source supplies two loads in parallel. The warm lime softening process operates in the temperature range of 120140f 4960c. Uses lime caoh 2 and soda ash na 2 co 3 to reduce the hardness of the treated water by precipitating the dissolved calcium and magnesium salts as insoluble calcium carbonate and magnesium hydroxide respectively. In lime soda ash softening plants, the softening process may be carried out by a.

Magnesium carbonate mgco 3, unlike calcium carbonate, does not precipitate in cold water. The solubilities of calcium, magnesium, and silica are reduced by increased temperature. The solubilities of calcium, magnesium, and silica are reduced by. In cold softening process the lime either hydrated lime caoh2 or. Hot and cold lime soda process 10th lecturer by ruchi upadhyay. In the hot lime soda process the reactions take place at higher temperature near about boiling point of water. The precipitates formed are very fine so the use of coagulants is essential. In this method, calculated quantity of chemical like lime and soda are mixed with water at. Precipitation of magnesium hydroxide produces water quality benefits, but can also cause operational problems and increase expenses for a water utility.

The types of lime soda softening process include the use of lime caoh 2 with soda ash na 2 co 3, the use of caustic soda naoh and the use of. In small systems, lime softening is typically practiced by adding hydrated lime to raw water to. Soda lime is a process used in water treatment to remove hardness from water. Chemicals normally used are lime calcium hydroxide, caoh 2 and soda ash sodium carbonate, na 2co 3. Sketch a drawing of a typical lime softening facility, identifying processes and points of chemical addition in the appropriate order for each of the following.

Magnesium is removed due to the precipitation of magnesium hydroxide. Advantages and disadvantages of cold lime soda process. Calculated amount of slaked lime caoh 2 added to hard water. Cold lime soda process sodium carbonate calcium scribd. There are three main types of lime softening systems. Explain hot and cold lime soda process with the help of diagram. Lime soda ash softening is assumed to be capable of reducing calcium and magnesium to empirically determined practical limits of 0. The chemical mixing process is same as the cold lime. Jan 22, 2014 hot lime soda process in the hot lime soda process the reactions take place at higher temperature near about boiling point of water.

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